Scientists have worked for decades to get colloidal spheres to arrange themselves in sparser lattices, which would unleash potentially valuable optical properties. The structures, called photonic crystals, could increase the efficiency of lasers, make optical components even smaller, and increase engineers’ ability to control the flow of light.
Now, New York University researchers report a pathway toward the self-assembly of these elusive photonic crystal structures never assembled before on the sub-micrometer scale.
Their research introduces a new design principle based on preassembled components of the desired superstructure, much as a prefabricated house begins as a collection of pre-built sections.
The researchers report they were able to assemble the colloidal spheres into diamond and pyrochlore crystal structures — a particularly difficult challenge because so much space is left unoccupied.
The team took inspiration from a metal alloy of magnesium and copper that occurs naturally in diamond and pyrochlore structures as sub-lattices. They saw that these complex structures could be decomposed into single spheres and tetrahedral clusters (four spheres permanently bound).
[caption id="attachment_4089” align="aligncenter” width="680”] The superlattice is made up of two interpenetrating sublattices, one diamond, shown in green, and the other pyrochlore, shown in red. Preformed red tetrahedral clusters and green spheres self-assemble into a MgCu2 superlattice. (Credit: David Pine, Etienne Ducrot, Gi-Ra Yi)[/caption]
To realize this in the lab, they prepared sub-micron plastic colloidal clusters and spheres, and employed DNA segments bound to their surface to direct the self-assembly into the desired superstructure.
says Etienne Ducrot, a postdoctoral researcher at the New York University Center for Soft Matter Research.
Open Colloidal Crystals
Ducrot says open colloidal crystals, such as those with diamond and pyrochlore configurations, are desirable because, when composed of the right material, they may possess photonic band gaps—ranges of light frequency that cannot propagate through the structure—meaning that they could be for light what semiconductors are for electrons.
Coauthor David J. Pine, chair of the chemical and biomolecular engineering department at NYU Tandon School of Engineering, adds that self-assembly technology is critical to making production of these crystals economically feasible because creating bulk quantities of crystals with lithography techniques at the correct scale would be extremely costly and very challenging.
Original Study: Colloidal alloys with preassembled clusters and spheres
Top Image: Leon Hupperichs CC BY-SA 3.0