A new technique called “photo-induced force microscopy,” which probes the optical properties of nanomaterials by measuring the physical force imparted by light, is being tested by scientists at Rice University.
Isabell Thomann’s primary research centers on using nanoparticles and sunlight to reduce the carbon footprint of power plants. A major focus is photocatalysis, a class of processes in which light interacts with high-tech materials to drive chemical reactions.
says Thomann, an assistant professor of electrical and computer engineering, materials science, nanoengineering, and chemistry at Rice University.
Ultrafast Laser Spectroscopy
Thomann has been working to develop new tools for measuring nanomaterials since arriving at Rice in 2012. She and her team are developing an ultrafast laser spectroscopy system that can read the optical signatures of short-lived chemical processes that are relevant to artificial photosynthesis.
Thomann’s group designs light-activated nanoparticles that can capture energy from sunlight and use it to initiate chemical reactions.
[caption id="attachment_4050” align="aligncenter” width="680”] Images show the measured optical forces for an array of plasmonic gold disc pairs known as dimers that were probed by an atomic force microscopy tip. The map reveals slight differences caused by minute imperfections in the dimers. (Credit: the Thomann Group/Rice with permission from Nano Letters 2016, Articles ASAP, DOI: 10.1021/acs.nanolett.6b04245. © 2016 American Chemical Society)[/caption]
The nanocatalysts, which can be tiny rods or discs of metal or other materials, interact with light due in part to their shapes and how closely they are spaced together. Thomann says that while engineers make every effort to produce uniform particles, small imperfections still exist and can have significant consequences on performance.
In the photon-induced force microscopy experiments, Thomann’s team used a tiny tip from an atomic force microscope (AFM) to enhance the spatial resolution of measurements taken from gold nanorods and nanodiscs on glass surfaces.
The rods and discs, which are smaller than the wavelength of light used to measure them, would normally be blurry in an optical microscope due to a physical property called the diffraction limit.
To better resolve the nanoparticles, and the electromagnetic interactions between them, Thomann’s group shines light at the particles and uses an AFM tip to probe how these nanoparticles act as optical nanoantennas and concentrate the light.
It turns out that measuring the force is a much more sensitive technique than trying to collect the few photons scattered off the tip.”
New Photocatalyst Materials
Thomann says the study provides theoretical understanding of how photo-induced force microscopy works and lays the groundwork for future studies of more complex photocatalyst materials her team hopes to create in the future. She credits her group’s improved understanding of the force-measuring technique to work by coauthor Xiao Yang, a Rice graduate student in the group of theoretical physicist and study coauthor Peter Nordlander.
Yang says the most difficult part of coming up with an explanation of the team’s experimental results was creating a solvable computational model that accurately described the real-world physics. For example, including the entire tip in the model made the mathematics impractical.
Yang eventually hit upon an idea, including just a portion of the tip in the model, that made the calculations both feasible and accurate.
Original Study: Photoinduced Force Mapping of Plasmonic Nanostructures
Top Image: Materialscientist CC BY-SA 3.0