Liquid-based Batteries Could Run On Fluorescent Dye

A glow-in-the-dark dye be the next advancement in energy storage technology, say scientists at the University at Buffalo. They have fingered a fluorescent dye called boron-dipyrromethene as an ideal material for stockpiling energy in rechargeable, liquid-based batteries that could one day power cars and homes.

Boron-dipyrromethene (BODIPY) shines brightly in the dark under a black light, but the features that facilitate energy storage are less visible.

According to new research, the dye has unusual chemical properties that enable it to excel at two key tasks: storing electrons and participating in electron transfer. Batteries must perform these functions to save and deliver energy, and BODIPY is very good at them.

Redox Flow Batteries

In experiments, a BODIPY-based test battery operated efficiently and with longevity, running well after researchers drained and recharged it 100 times.

Lead researcher Timothy Cook, PhD, an assistant professor of chemistry in the University at Buffalo College of Arts and Sciences, said:

BODIPY is a promising material for a liquid-based battery called a “redox flow battery.”

These fluid-filled power cells present several advantages over those made from conventional materials.

Lithium-ion batteries, for example, are risky in that they can catch fire if they break open, Cook says. The dye-based batteries would not have this problem; if they ruptured, they would simply leak, he says.

[caption id="attachment_4020” align="aligncenter” width="680”]BODIPY To make the dye solution used in the test battery, the research team mixed dark red BODIPY crystals (right) into a clear solvent called acetonitrile (left). Credit: Douglas Levere[/caption]

Redox flow batteries can also be easily enlarged to store more energy, enough to allow a homeowner to power a solar house overnight, for instance, or to enable a utility company to stockpile wind energy for peak usage times. This matters because scaling up has been a challenge for many other proposed battery technologies.

How A Boron-dipyrromethene Battery Works

Redox flow batteries consist of two tanks of fluids separated by various barriers.

When the battery is being used, electrons are harvested from one tank and moved to the other, generating an electric current that—in theory—could power devices as small as a flashlight or as big as a house.

To recharge the battery, you would use a solar, wind or other energy source to force the electrons back into the original tank, where they would be available to do their job again.

[caption id="attachment_4021” align="aligncenter” width="680”]First author Anjula M. Kosswattaarachchi First author Anjula M. Kosswattaarachchi, a UB PhD student in chemistry, holds a volumetric flask containing BODIPY dye. Credit: Douglas Levere[/caption]

A redox flow battery’s effectiveness depends on the chemical properties of the fluids in each tank.

In experiments, Cook’s team filled both tanks of a redox flow battery with the same solution: a powdered BODIPY dye called PM 567 dissolved in liquid.

Within this cocktail, the BODIPY compounds displayed a notable quality.

They were able to give up and receive an electron without degrading as many other chemicals do. This trait enabled the dye to store electrons and facilitate their transfer between the battery’s two ends during repeated cycles—100—of charging and draining.

Based on the experiments, scientists also predict that BODIPY batteries would be powerful enough to be useful to society, generating an estimated 2.3 volts of electricity.

The study focused on PM 567, different varieties of BODIPY share chemical properties, so it’s likely that other BOPIDY dyes would also make good energy storage candidates, Cook says.

Study: Characterization of a BODIPY Dye as an Active Species for Redox Flow Batteries

Top Image: A glowing solution of BODIPY dye under a black light. Credit: Douglas Levere

See also