A new strategy for forming 3D shapes from flat, 2D sheets of graphene, has been developed by researchers from the University of Illinois at Urbana-Champaign. The approach opens the door to future integrated systems of graphene-MEMS hybrid devices and flexible electronics.
SungWoo Nam, assistant professor of mechanical science and engineering at Illinois, explained:
The flexibility and 3D nature of our structures will enable intimate biosensing devices which can be conformed to the shape and characteristics of human skin and other biological systems. The 3D protruding micro-structures can also achieve enhanced sensitivity by maximizing the effective contact area between the sensors and non-flat surfaces.
We also expect that our new 3D integration approach will facilitate advanced classes of hybrid devices between microelectromechanical systems (MEMS) and 2D materials for sensing and actuation.“
The researchers’ robust approach to integrating graphene in 3D microstructured surfaces maintains the structural integrity of graphene, where the out-of-plane dimensions of the 3D features vary from 3.5 to 50 μm.
The process is comprised of three steps:
- substrate swelling using a solvent that
- shrinks during the evaporation process, allowing graphene to
- adapt, or conform to the shape of a prepared substrate, to achieve damage-free, large area integration of graphene on 3D microstructures
First author Jonghyun Choi, a graduate student in Nam’s research group, Said:
Graphene is a two-dimensional honeycomb lattice of sp2-bonded carbon atoms. It has been widely studied due to its high carrier mobility, chemical inertness, and biocompatibility.
Various reported methods of graphene transfer have been mostly limited to planar or curvilinear surfaces due to the challenges associated with fractures from local stress during transfer onto 3D microstructured surfaces.
Detailed scanning electron microscopy, Raman spectroscopy, atomic force microscopy, and electrical resistance measurement studies demonstrate that the amount of substrate swelling, as well as the flexural rigidities of the transfer film, affect the integration yield and quality of the integrated graphene.
To show the versatility of their approach, the researchers applied the process to a variety of 3D microstructured geometries, as well as integrating hybrid structures of graphene decorated with gold nanoparticles onto 3D microstructure substrates, demonstrating the compatibility of the integration method with other hybrid nanomaterials.
Jonghyun Choi, Hoe Joon Kim, Michael Cai Wang, Juyoung Leem, William P. King, and SungWoo Nam Three-Dimensional Integration of Graphene via Swelling, Shrinking, and Adaptation Nano Lett., DOI: 10.1021/acs.nanolett.5b01036
Illustration: graphene integration to a variety of different microstructured geometries, including pyramids, pillars, domes, and inverted pyramids. Credit: Nam Research Group, University of Illinois